Although the polyacetylene
film shone like silver, it was not an electrical
conductor. Could it perhaps be modified in some
way? In the mid-1970s the three Laureates began
co-operating to investigate this and results were
quick to come. When they caused the films to
react with iodine vapour, the conductivity
increased by as much as ten million times –
a discovery that was eventually to give them a
Nobel Prize in Chemistry.
Oxidation with iodine causes the electrons
to be jerked out of the polymer, leaving
"holes" in the form of positive charges that
can move along the chain.