by Christophe
Lécuyer
Hoerni developed a new manufacturing process which relied heavily
on the masking and passivating properties of sillicon oxide.
Under the mesa process the oxide layer was deposited on after the
making of the base in order to mask the emitter diffusion and was
later removed. Hoerni grew an oxide layer on top of the wafer at
the very beginning of the process and used it to mask both the
base and the emitter. More importantly, Hoerni, in a very
innovative move, left the oxide layer on top of the wafer after
transistor processing. This went against all accepted knowledge
in the silicon community: It is widely believed at the time among
practitioners of the silicon art that the oxide layer used to
mask dopants was dirty and, as a result, had to be etched away.
Instead, Hoerni, a self professed "contrarian," left the oxide
layer on top of the wafer. He then made the startling discovery
that far from contaminating the wafer, it passivated the
crystal's surface and protected the transistor junctions from
outside contaminants. Exploiting these basic ideas, Hoerni built
his process around seven basic steps. Starting with an N-type
wafer (a), Hoerni carefully oxidized it by exposing it to an
oxygen carrier gas in a high temperature furnace. Using the
photolithographic techniques developed for Fairchild's first mesa
transistor, he then selectively etched the oxide (b). In the next
step (c), Hoerni exposed the wafer to a boron vapor, another
standard process at Fairchild, to create the transistor's base.
As the boron atoms diffused both vertically and horizontally, the
junction between the collector and the base moved laterally and
was protected from outside contaminants by the oxide layer.
Hoerni later reoxidized the exposed area. Applying another
masking and etching process (d), he opened a window into the
regrown oxide of the base area. He then diffused phosphorus to
form the emitter (e), creating a base-emitter junction. This
junction, like the base to collector junction, was protected from
outside contamination by the silicon oxide. After diffusing the
emitter, Hoerni again selectively etched the oxide layer to
provide for alloy contacts (f). Finally (g), he deposited
contacts on the etched areas and alloyed them in.
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Source: Jean Hoerni, "Planar Silicon Transistors and
Diodes," Paper presented at the 1960 Electron Devices Meeting,
Washington, D.C. - October 1960, Bruce Deal Papers, 88-033,
Stanford Archives and Special Collections.